•  
  •  
  •  
  •  
  •  
  •  
  •  
  •  
期刊检索


检索
检索项:
检索词:
总目录
  • WCSB9︱2019(第九届)世界采样和混样大会 查看全文>>
  • 关于召开第十五届全国青年分析测试学术报告会的通知 查看全文>>
友情链接
表面增强拉曼光谱结合主成分分析快速筛查食品接触材料中多环芳烃
    点此下载全文
作者单位
葛琨,何致峰,林佳娜,胡玉玲,李攻科 中山大学 化学学院广东 广州 510275 
基金项目:国家重点研发计划(2018YFC1603201,2018YFC1603200)
中文摘要:建立了表面增强拉曼/主成分分析快速筛查食品接触材料中4种多环芳烃的分析方法。采用纳米银溶胶作为增强基底,碘化钾为絮凝剂,实现了4种多环芳烃(芘、荧蒽、苯并[b]荧蒽、苯并[k]荧蒽)的表面增强拉曼分析。针对食品接触材料中4种多环芳烃拉曼谱峰重叠难以鉴别区分的问题,采用主成分分析法分别对同浓度多环芳烃、不同浓度多环芳烃以及多环芳烃混合样品进行分析。结果表明,4种多环芳烃均可得到较好的鉴别。该方法成功用于食品接触材料迁移液中4种多环芳烃的快速筛查。
中文关键词:表面增强拉曼光谱  主成分分析  食品接触材料  多环芳烃  快速筛查
 
Rapid Screening of Polycyclic Aromatic Hydrocarbons in Food Contact Materials by Surface-enhanced Raman Spectroscopy Combined with Principal Component Analysis
Abstract:Analysis of polycyclic aromatic hydrocarbons(PAHs) has drawn great attention due to their high bio-accumulative,carcinogenic and teratogenic properties.PAHs might migrate to foods through contaminated food contact materials(FCMs),causing huge potential damages to human health.It is very important to screen PAHs in FCMs with high rapidity and accuracy.Surface-enhanced Raman spectroscopy(SERS) is a promising optical tool for contaminants screening due to its unique properties of rapidity,sensitivity and molecule fingerprint characteristic.However,PAHs is a class of pollutants including over 200 chemicals with two or more benzene rings,meaning the similar structure and overlapping of characteristic Raman peaks.Principal component analysis(PCA) is an ideal data processing method,which could be used to extract useful information from large amount of data by dimensionality reduction process.Researchers have developed methods for identifying chemicals with similar structure by SERS combined with PCA method,obtaining good segregation and identification results.In this paper,a simple analytical method was established for rapid screening of four PAHs,i.e.pyrene(Pyr),fluoranthene(FlA),benzo[b]fluorathene(BbF) and benzo[k]fluorathene(BkF) in FCMs of polyethylene terephthalate(PET) and polypropylene(PP) based on the combination of SERS and PCA.Ag nanoparticles(AgNPs) were mixed with inorganic salt of potassium iodide(KI) to form the aggregated AgNPs with denser“hot spot”,which were used as the enhanced substrate for SERS analysis with high sensitivity.In order to obtain the optimum sensitivity,some analytical parameters including inorganic salt,concentration of KI,incubation time and volume ratio of KI∶BbF∶AgNPs were optimized.Under the optimum conditions,the Raman characteristic peak of Pyr,FlA,BbF and BkF were recorded and sorted for next PCA analysis.Afterwards,PCA method was adopted for the rapid identification of four PAHs to overcome the overlapping of characteristic peaks with similar structure.Results showed that the four PAHs could be easily and obviously identified in the same or different concentration or mixed samples.In addition,the minimum tolerance method was used for identifying PAHs in mixed samples with better segregation and identification results,indicating that the minimum tolerance method could eliminate interference of mixed PAHs samples with similar structure.Furthermore,two FCMs including PET and PP were migrated in 95%(by volume) ethanol at 100 ℃ for 4 h to evaluate the feasibility and accuracy.The migration of PAHs in PET and PP FCMs were rapidly screened and identified based on the established method with satisfactory results,indicating the practicability and accuracy of the PCA-SERS method.The developed method shows great potentials in rapid screening of four PAHs in FCMs migration with high rapidity,accuracy and practicability,which could be used to monitor the safety of FCMs containing PAHs.Also,the method could be used for the detection and screening of other contaminants in FCMs.
Key Words:surface-enhanced Raman spectroscopy  principal component analysis  food contact materials  polycyclic aromatic hydrocarbons  rapid screening
引用本文:葛琨,何致峰,林佳娜,胡玉玲,李攻科.表面增强拉曼光谱结合主成分分析快速筛查食品接触材料中多环芳烃[J].分析测试学报,2021,40(11):1588-1595.
摘要点击次数: 89
全文下载次数: 173
查看全文  下载PDF阅读器