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超分子溶剂在样品前处理与检测技术中的应用研究进展
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作者单位
陈萌,刘艺静,郭兴洲,白桦,马强 1. 中国检验检疫科学研究院北京 100176 2. 北京中医药大学 中药学院北京 102488 
基金项目:国家自然科学基金面上项目(21974129)
中文摘要:随着绿色分析化学概念的提出,新型绿色溶剂的开发和利用成为当前的研究热点。将绿色溶剂替代传统有机溶剂用于样品前处理过程,可以减少对实验人员及环境的危害。超分子溶剂由于两亲物质含量高,萃取分离条件温和,近年来被广泛应用于萃取富集宽极性范围内的目标分析物,兼具萃取和净化的效果。该文介绍了超分子溶剂的形成过程和基本性质,综述了超分子溶剂应用于萃取分离过程的优势,对超分子溶剂在样品前处理中的应用进行了归纳梳理,包括基于超分子溶剂的样品前处理及超分子溶剂萃取与其他前处理方式的联用,并对超分子溶剂萃取与多种检测技术的联用进行了介绍。通过对超分子溶剂在样品前处理与检测技术中应用研究进展的综述,为其进一步开发利用提供理论指导和技术支持。
中文关键词:超分子溶剂  样品前处理  检测技术  综述
 
Advances on Applications of Supramolecular Solvents in Sample Pretreatment and Analytical Techniques
Abstract:With the introduction of concept of green analytical chemistry,the development and utilization of novel green solvents have become a hot topic in contemporary research.Application of green solvents replacing traditional organic solvents in sample pretreatment could reduce the harm to laboratory personnel and the environment.Supramolecular solvents(SUPRASs) have been extensively used for the extraction and enrichment of the target analytes with wide polarity ranges in recent years due to their high-content amphiphilic substances and mild extraction and separation conditions,achieving both extraction and clean-up effects.In this paper,the formation process and basic properties of SUPRASs are introduced.Their advantages in extraction and separation are summarized. The applications of SUPRASs in sample pretreatment are reviewed,including the extraction of target substances by SUPRASs alone or in combination with other pretreatment methods.Combinations of SUPRASs-based extraction with various analytical techniques are also summarized.A systematic overview on the research advances of SUPRASs in sample pretreatment and analytical techniques may provide a theoretical guidance or technical support for their further development and utilization.
Key Words:supramolecular solvents(SUPRASs)  sample pretreatment  analytical techniques  review
引用本文:陈萌,刘艺静,郭兴洲,白桦,马强.超分子溶剂在样品前处理与检测技术中的应用研究进展[J].分析测试学报,2022,41(1):22-31.
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