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| Synthesis and Characterization of Mesoporous Zirconia with High Thermal Stability |
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| DOI：10.3969/j.issn.1004-4957.年份.月份 |
| KeyWord:anionic surfactant mesoporous zirconia thermal stability |
| Author | Institution |
| 朱富强，王宗花,夏建飞，张菲菲，夏延致,李延辉 |
1.青岛大学纤维新材料与现代纺织实验室国家重点实验室培育基地;2.青岛大学化学化工与环境学院 |
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| Abstract: |
| Mesoporous zirconia samples with high thermal stability were synthesized by hydrothermal homogeneous precipitation method using an anionic surfactant as template.In this method,sodium dodecyl benzene sulfonate（SDBS) not only functioned as a directing agent for mesoporous structure but also functioned as a mesoporous structure stabilizer with the sulfonic groups converted to SO2-4after calcination.The samples were characterized by TEM,nitrogen adsorption-desorption isotherms,XRD and FT-IR.The N2 adsorption analysis showed that the zirconia still has a surface area of 156 m2/g after calcination at 500 ℃.The TEM analysis displayed that it has a worm-like mesoporous structure with a pore size about 2.9 nm.The XRD analysis displayed that the prepared zirconia continuous to present a pure tetragonal phase,with good thermal stability even calcinated at 600 ℃. |
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