Colorimetric Detection of Silver Ions Based on Au@Pt Nanoparticles
  
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KeyWord:Au@Pt nanoparticles  enzyme mimics  colorimetric detection  Ag+  Hg2+
  
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CHEN Ming-ming,WU Liang-liang,XIE Zheng-jun,PENG Chi-fang* 江南大学食品学院食品科学与技术国家重点实验室
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Abstract:
      Au@Pt NPs have an excellent peroxidase like activity,and silver ions(Ag+) could intensively inhibit the catalytic ability of Au@Pt NPs.Based on this,a colorimetric detection of Ag+ was performed in a linear range of 0.1- 10 nmol/L with a detection limit of 0.05 nmol/L.The sensing system also showed a sensitive response to Hg2+.A linear range of 10-200 nmol/L and a detection limit of 5.0 nmol/L were achieved in the colorimetric detection for Hg2+.The method was applied in detection of tap water spiked with Ag+(10,50,100 nmol/L),and the recoveries ranged from 83.8% to 97.7% with relative standard deviations(RSD) of 3.0%-9.6%.This method has the advantages of simplicity,sensitivity and low cost.
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